T. H. Burbine

Spectral Properties of Near-Earth Asteroids: Evidence for Sources of Ordinary Chondrite Meteorites

Although ordinary chondrite (OC) meteorites dominate observed falls, the identification of near-Earth and main-belt asteroid sources has remained elusive. Telescopic measurements of 35 near-Earth asteroids (∼3 kilometers in diameter) revealed six that have visible wavelength spectra similar to laboratory spectra of OC meteorites. Near-Earth asteroids were found to have spectral properties that span the range between the previously separated domains of OC meteorites and the most common (S class) asteroids, suggesting a link. This range of spectral properties could arise through a diversity of mineralogies and regolith particle sizes, as well as through a time-dependent surface weathering process.

Reflectance calibrations of AXAF mirror samples at absorption edges using synchrotron radiation

We are developing a system to calibrate reflectances of witness coupons to the AXAF flight mirrors at the National Synchrotron Light Source over the 0.05-12 keV energy range. These witness coupons will be coated in the same process as the AXAF mirror elements. One of the key issues is the accurate determination of mirror efficiencies across the absorption edges of the mirror coating elements. We present a series of reflectance measurements with 2 eV resolution of a nickel-coated flat mirror in the region of the Ni L-II (870 eV) and L-III (853 eV) absorption edges. Scans of reflectance versus grazing angle at fixed energies in this region show distinct interference fringes at grazing angles larger than the critical angle which are extinguished as the photon energy is increased beyond the low point of the L-III edge, indicating total absorption of the evanescent wave within the Ni film. At 51 arc minutes grazing angle, measured reflectance decreases smoothly by 35 percent and then recovers in an 8 eV band at the L-III edge. We have also measured reflectances in the M absorption edge region for gold, platinum, and iridium coated mirrors. We derive optical parameters n and k specific to the film for comparison to the existing data tables.

Molecular contamination study of iridium-coated x-ray mirrors

We have completed extensive synchrotron reflectivity measurements on several iridium mirrors which were intentionally coated with thin layers (100 angstroms or less) of polyethylene, a hydrocarbon contaminant. The purpose was to verify theoretical predictions of alterations in reflection efficiency of an iridium surface for various thicknesses of hydrocarbon contamination, and to evaluate the acceptability of attainable upper limits of such contamination for the mirrors aboard NASAs Advanced X-ray Astrophysics Facility (AXAF). Although the deposition of such thin layers is problematic with no systematic guarantee of uniform thickness or density, successful analysis by modeling the contaminant as a uniform surface layer may be done, within a limited X-ray energy range. The M-edges of iridium are significantly affected by the polyethylene layers. For the most part, contamination increases the reflectance in the M-edge range over that of bare iridium, although cross-over points between contaminated and uncontaminated mirrors occur at several angles relevant to AXAF. However, calibratability of the reflectance is a more significant issue than X-ray mirror efficiency. We present the modeling results for three thicknesses of polyethylene, and discuss the implications for the performance of AXAF mirrors and their calibratability.

Asteroid Spectroscopy and Mineralogy

Spectroscopic observations of asteroids of smaller sizes and in the near-infrared have led to many exciting discoveries that have increased substantially our knowledge of the mineralogy of asteroids. These discoveries include the identification of hydrated M and E-asteroids, the mineralogical diversity of the S-class, anomalous S-asteroids, a possible source body of the aubrites, Vesta-like objects in the main belt, possible ordinary chondrite-like objects and one of the reddest objects in the solar system.

Optical constants from mirror reflectivities measured at synchrotrons

Improved mirror reflectivity measurement techniques have been introduced to permit more accurate determinations of optical constants delta and beta in the complex index of refraction n = 1 - delta - i(beta) over the energy range 50 to 5000 eV. When the density has been determined by X-ray or other means, one can calculate the real and imaginary parts, f-prime and f-double prime, of the complex atomic scattering factor f = f(o) + f-prime + if-double prime from delta and beta. Preliminary results are given for the Ni LIII edge around 852 eV, and the Au M edge region from 2150 to 3500 eV. Since these are the first experimental evaluations of delta for these element edges, they are compared with appropriate reservations to semiempirical tabulations. There is much potential for this technique applied to synchrotron sources.