Thomas Mülders

Impact of photoresist composition and polymer chain length on line edge roughness probed with a stochastic simulator

The impact of various parameters such as photoacid generator (PAG) concentration, acid diffusion length, and polymer size on the finally obtained line edge roughness (LER) in chemically amplified photoresists are investigated with a stochastic simulator. A new aspect of the simulations is to start with a polymer matrix modeled by molecular dynamics simulation and subsequently simplify the description of the resist composition for mesoscopically simulating the post-exposure bake (PEB) and development steps. The results show that decreasing the molecular weight (MW) of chain-like polymers does not necessarily lead to lower roughness values. Acid-breakable polymers are simulated as well showing that they can lead to improved LER characteristics.

New stochastic post-exposure bake simulation method

A new method for simulating the post-exposure bake (PEB) of optical lithography is presented and applied to modeling the reaction-diffusion processes in a chemically amplified resist (CAR). The new approach is based on a mesoscopic description of the photoresist, taking into account the discrete nature of resist molecules and inhibitor groups that are attached to the resist polymers, but neglecting molecular details on an atomistic (microscopic) level. As a result, the time- and space-dependent statistical fluctuations of resist particle numbers, the correlations among them, and their effect on the printing result can be accounted for. The less molecules that are present in the volume of interest, the more important these fluctuations and correlations will become. This is the case for more and more shrinking critical dimensions (CD) of the lithographic structures but unchanged molecular sizes of the relevant resist species. In particular, the new PEB simulation method allows us to predict the behavior of statistical defects of the printed lithographic structures, which may strongly contribute to printing features like line edge roughness (LER).

OPC with customized asymmetric pupil illumination fill

Sophisticated designs of the pupil illumination fill of scanners and steppers permit considerable improvements of the resolution and the quality of the optical projection for certain critical patterns. However, the mask layout can have quite different requirements for the resolution as well as the shape of the critical patterns in the two spatial directions. For instance, typical DRAM designs have one orientation with much higher requirements than the other orientation. This asymmetry can be accounted for with a corresponding pupil fill that has a reduced symmetry as well. It is for example possible to combine high resolution and high contrast of the most critical pattern in one spatial orientation at the cost of the other orientation. Unfortunately, this leads to an asymmetric source distribution with x-y dependent optical proximity effects. Therefore the transfer of one and the same pattern from the mask to the wafer will differ if this pattern is rotated by 90 degrees. But fortunately, this anisotropic mapping can be compensated by applying an appropriate optical proximity correction (OPC) which is anisotropic as well. In the current work, we measure on silicon the orientation dependent proximity effect for a customized and strongly asymmetric pupil illumination fill design. With this input data, we build a lithography simulation model which is able to reproduce this anisotropy well. We further perform full chip anisotropic OPC and present the actual success of this resolution enhancement technique with various measurement results and printed wafer images. We also discuss the challenges and problems of this method.