Kuniaki Sueoka

IMC bonding for 3D interconnection

We performed stacking experiments on Si dies using annular tungsten TSVs (Through Silicon Vias) and Cu studs with low-volume solder micro-bumps. Unlike standard 100-micron C4 (Controlled Collapse Chip Connection) solder balls, very small solder volumes (< 6 microns in height) form IMC (InterMetallic Compounds) in the junctions during the bonding or reflow processes. The two interconnect metallurgies of Cu/Ni/In and Cu/Sn joints were considered for low-volume lead-free solder micro-bumps for 3D integration. A previous study on these metallurgies [5] showed that the Cu/Sn joints form thermally stable intermetallics while in the Cu/Ni/In joints, some indium solder remains unreacted due to the presence of the Ni barriers. The shear testing on the stacked systems showed that the die stacks with Cu/Sn joints exhibit higher shear strengths than those with Cu/Ni/In joints. However the impact shock testing on the systems revealed that the die stacks with Cu/Sn joints are less resistant to mechanical shocks than the systems with Cu/Ni/In joints. This new work focuses on thermal cycle testing of the die stack systems with the Cu/Ni/In and Cu/Sn interconnections. Preliminary thermal cycle testing on the die stack systems with Cu/Ni/In joints showed that the joints are stable against thermal cycle stresses for thousands of cycles. To quickly compare the systems with two metallurgies, we mounted the Si die stacks onto organic substrates to impose additional stresses on the systems. In addition to standard DTC (Deep Thermal Cycle) tests, we also conducted a HAATS (Highly accelerated Air to Air Thermal Shock) test [23] with a short cycle time to reduce the testing time. The DTC and HAATS tests showed that the stacked systems with Cu/Ni/In joints had fewer failures and smaller increases in the electrical resistances of the joints during the tests than the systems with Cu/Sn joints.

Characterization of stacked die using die-to-wafer integration for high yield and throughput

We have developed a die-to-wafer integration technology for high yield and throughput for the formation of high bandwidth, high performance, and short-distance interconnections in three-dimensional (3D) stack applications. The results show that multiple 70-mum thick die can be successfully assembled in stacks on top of a wafer using a single bonding step, rather than by repeated sequential bonding steps. In this study, 1-die, 3-die, and 6-die stacks were assembled and the electrical resistance of link chains consisting of through-silicon-vias (TSVs), low-volume lead-free interconnects, and Cu wiring links was measured. The average resistance of the TSV including the lead-free interconnect was as low as 21 mOmega. The stacking throughput can be dramatically improved by this die-to-wafer integration technology and the contact resistance and reliability test results suggest that a reliable integration technology can be used for 3D stack applications.

Development of vacuum underfill technology for a 3D chip stack

We developed a vacuum underfill technology for 3D chip stacks and for flip chips in high performance system integration. We fabricated a 3D prototype chip stack using the vacuum underfill technology to apply the adhesive. The underfill was injected into each 6 µm gaps in a 3-layer chip stack and no voids were detected in acoustic microscopy images. Electrical tests and thermal reliability tests were used to measure the resistance of the vertical interconnections and the impact of the underfill. The results showed there was minimal difference in the average interconnection resistance of the chip stack with and without underfill.

Experimental thermal resistance evaluation of a three-dimensional (3D) chip stack

To propose an appropriate cooling solution for a three-dimensional (3D) chip stack at the design phase, it is necessary to estimate the total thermal resistance of a 3D chip stack. The interconnection between stacked chips is considered as one of the thermal resistance bottleneck of a 3D chip stack, but it is not experimentally clear yet. We have previously measured the thermal conductivity of SnAg with Cu post to be 37–41W/mC by a steady state thermal resistance measurement method, using the sample which was simply composed of two Si chips and SnAg with Cu post between two Si chips. In this study, 3D stacked test chips are fabricated, which are implemented with PN junction diodes for temperature sensors and diffused resistors for heating, and the thermal conductivity of the interconnection in actual 3D stacked structure is experimentally obtained. The temperature distributions of two 3-layer-stacked-test-chips are measured and the equivalent thermal conductivity of the interconnection is experimentally obtained to be 1.6W/mC. This value is compared with the measured thermal conductivity of SnAg with Cu post (37–41W/mC) and its adequacy is examined.

Experimental thermal resistance evaluation of a three-dimensional (3D) chip stack, including the transient measurements

For the thermal management of three-dimensional (3D) chip stack, its thermal resistance needs to be clearly understood. In this study, 3D stacked test chips are fabricated, which are implemented with PN junction diodes for temperature sensors and diffused resistors for heating. At SemiTherm2011, the equivalent thermal conductivity of the interconnection, including BEOL (Back-End-Of-the-Line, wiring layer) is experimentally obtained to be 1.6W/mC and this time, we measure the thermal effect of Cu TSVs and it is experimentally supported that as the Cu TSV area ratio increases, the thermal conductivity of chip with TSVs in the vertical direction increases, on the contrary, that in the horizontal direction decreases. Also, the transient thermal measurement is performed and its result is compared with steady state measurement result. Further, the thermal capacitance measurement of 3D stacked test chip with hot spot heating is performed, which is essential to determine the transient thermal performance of 3D chip stack.

Through silicon via process for effective multi-wafer integration

We propose a novel 3D integration method, called Vertical integration after Stacking (ViaS) process. The process enables 3D integration at significantly low cost, since it eliminates costly processing steps such as chemical vapor deposition used to form inorganic insulator layers and Cu plating used for via filling of vertical conductors. Furthermore, the technique does not require chemical-mechanical polishing (CMP) nor temporary bonding to handle thin wafers. The integration technique consists of forming through silicon via (TSV) holes in pre-multi-stacked wafers (> 2 wafers) which have no initial vertical electrical interconnections, followed by insulation of holes by polymer coating and via filling by molten metal injection. In the technique, multiple wafers are etched at once to form TSV holes followed by coating of the holes by conformal thin polymer layers. Finally the holes are filled by using molten metal injection so that a formation of interlayer connections of arbitrary choice is possible. In this paper, we demonstrate 3-chip-stacked test vehicle with 50 × 50 μm-square TSVs assembled by using this technique.

Fluxless bonding for fine-pitch and low-volume solder 3-D interconnections

Fluxless bonding can be used for fine-pitch low-solder-volume interconnections for three-dimensional large-scale integrated-circuit (3D-LSI) applications. Surface treatments with hydrogen radicals, formic acid, vacuum ultraviolet (VUV), and Ar plasma were evaluated as candidate methods for fluxless bonding. Three-μm-thick Sn solders were evaluated for intermetallic-compound (IMC) bonding of 3D integration as a target material for fluxless bonding. X-ray photoelectron spectroscopy (XPS), Auger electron spectro-scopy (AES), time-of-flight secondary ion mass spectrometry (TOF-SIMS), a scanning electron microscope (SEM), and a focused ion beam scanning ion microscope (FIB-SIM) were used to examine the samples. The experiments shows solder oxides and organic contaminants on the surfaces of the micro-bumps were most effectively eliminated without flux by hydrogen radical treatment among various treatments we evaluated. Bonding strength was also improved by the hydrogen radical treatment, since the shear strength was more than 50 times stronger than that of the untreated samples.

TSV diagnostics by X-ray microscopy

TSV (Through Silicon Via) is one of the key elements for building 3D integrated silicon devices with high bandwidth interconnections. In this paper, we propose a diagnostic method for TSV defects by using X-ray projection microscopy. By optimizing the image contrast of the X-ray projection micrographs in reference to its X-ray intensity histogram, we could obtain the small defect features in TSVs fast and non-destructively. Comparison between this X-ray observation and the destructive cross sectional observation agreed very well. We also extended the implementation of this X-ray microscope diagnostic method to 8-in. full wafer observation. We investigated the wafers with copper-filled TSVs with 80 µm and 20 µm diameters, and confirmed the feasibility of this method for an in-line process monitoring.

43.1: Color Filterless Liquid Crystal Display Illuminated with LEDs

We have prototyped a 13.3-inch diagonal color filterless LCD illuminated with LEDs. A new color directional backlight combined with a microlens attached liquid crystal cell plate shows the feasibility of a new power efficient LCD with better color and lead-free features.

Bonding technologies for chip level and wafer level 3D integration

This paper provides a comparison of bonding process technologies for chip and wafer level 3D integration (3Di). We discuss bonding methods and comparison of the reflow furnace, thermo-compression, Cavity ALignment Method (CALM) for chip level bonding, and oxide bonding for 300 mm wafer level 3Di. For chip 3Di, challenges related to maintaining thin die and laminate co-planarity were overcome. Stacking of large thin Si die with 22 nm CMOS devices was achieved. The size of the die was more than 600 mm2. Also, 300 mm 3Di wafer stacking with 45 nm CMOS devices was demonstrated. Wafers thinned to 10 μm with Cu through-silicon-via (TSV) interconnections were formed after bonding to another device wafer. In either chip or wafer level 3Di, testing results show no loss of integrity due to the bonding technologies.