David J. Abdallah

Resist component leaching in 193 nm immersion lithography

The leaching of ionic PAGs from model resist films into a static water volume is shown to follow first order kinetics. From the saturation concentration and the leaching time constant, the leaching rate at time zero is obtained which is a highly relevant parameter for evaluating lens contamination potential. The levels of leaching seen in the model resists generally exceed both static and rate-based dynamic leaching specifications. The dependence of leaching on anion structure shows that more hydrophobic anions have lower saturation concentration; however, the time constant of leaching increases with anion chain length. Thus in our model system, the initial leaching rates of nonaflate and PFOS anions are identical. Investigation of a water pre-rinse process unexpectedly showed that some PAG can still be leached from the surface although the pre-rinse times greatly exceeded the times required for saturation of the leaching phenomenon, which are expected to correspond to complete depletion of leachable PAG from the surface. A model is proposed to explain this phenomenon through re-organization of the surface as the surface energy changes during the air/water/air contact sequence of the pre-rinse process.

193nm dual layer organic BARCs for high NA immersion lithography

Extending the resolution capability of 193nm lithography through the implementation of immersion has created new challenges for ArF B.A.R.C.s. The biggest of which will be controlling reflectivity over a wider range of incident angles of the incoming imaging rays. An optimum B.A.R.C. thickness will depend on the angle of incidence of the light in the B.A.R.C. and will increase as the angle increases. At high angles different polarization have different optimum thicknesses. These confounding effects will make it increasingly difficult to control reflectivity over a range of angles through interference effects within a single homogenous B.A.R.C. Unlike single layer B.A.R.C.s, multilayer B.A.R.C.s are capable of suppressing reflectivity through a wide range of incident angles. In fact, remarkable improvements in antireflective properties can be achieved with respect to CD control and through angle performance with the simplest form of a multilayer B.A.R.C., a dual layer. Here we discuss the attributes of an all organic dual layer B.A.R.C. through simulations and preliminary experiments. One attribute of an organic over inorganic B.A.R.C. in high-NA lithography is its ability to planarize topography. ArF scanners designed to meet the needs of the 45nm node will have a very small depth-of-focus (DOF) which will require planar surfaces.

Study of barrier coats for application in immersion 193-nm lithography

We will describe our barrier coat approach for use in immersion 193 nm lithography. These barrier coats may act as either simple barriers providing protection against loss of resist components into water or in the case of one type of these formulations which have a refractive index at 193 nm which is the geometric mean between that of the resist and water provide, also top antireflective properties. Either type of barrier coat can be applied with a simple spinning process compatible with PGMEA based resin employing standard solvents such as alcohols and be removed during the usual resist development process with aqueous 0.26 N TMAH. We will discuss both imaging results with these materials on acrylate type 193 nm resists and also show some fundamental studies we have done to understand the function of the barrier coat and the role of differing spinning solvents and resins. We will show LS (55 nm) and Contact Hole (80 nm) resolved with a 193 nm resist exposed with the interferometric tool at the University of New Mexico (213 nm) with and without the use of a barrier coat.

Image Reversal Trilayer Process Using Standard Positive Photoresist

Conventional trilayer schemes alleviate the decreasing photoresist budgets as well as satisfy the antireflection issues associated with high NA imaging. However, a number of challenges still exist with standard trilayer processing, most notable among which is the lack of broad resist compatibility and trade-offs associated with improving Si content, such as stability and lithography performance. One way to circumvent these issues is to use a silicon hard mask coated over a photoresist image of reverse tone to the desired pattern. Feasibility of this image reversal trilayer process was demonstrated by patterning of trenches and contact holes in a carbon hard mask from line and pillar photoresist images, respectively. This paper describes the lithography, pattern transfer process and materials developed for the image reversal trilayer processing.

Etching spin-on trilayer masks

Spin-on trilayer materials are increasingly being integrated in high density microfabrication that use high NA ArF lithography due to dwindling photoresist film thicknesses, lower integration cost and reduced complexity compared to analogous CVD stacks. To guide our development in spin-on trilayer materials we have established etch conditions on an ISM etcher for pattern transfer through trilayer hard masks. We report here a range of etch process variables and their impact on after-etch profiles and etch selectivity with AZ trilayer hard mask materials. Trilayer pattern transfer is demonstrated using 1st and 2nd minimum stacks with various pattern types. Etch recipes are then applied to blanket coated wafers to make comparisons between etch selectivities derived from patterned and blanket coated wafers.

Spin-on trilayer approaches to high NA 193nm lithography

New challenges face ArF bottom antireflection coatings (BARCs) with the implementation of high NA lithography and the concurrent increase use of spin-on hard masks. To achieve superior reflectivity control with high NA at least two semi-transparent ARC layers, with distinct optical indices, are necessary to effectively lower substrate reflectivity through a full range of incident angles. To achieve successful pattern transfer, these layers in conjunction with the organic resist, should be stacked with an alternating elemental composition to amplify vertical resolution during etch. This will circumvent the inherent low etch resistance of ArF resist and the decreasing film thicknesses that accompanies increasing NA. Thus, incorporating hard mask properties and antireflection properties in the same two layer system facilitates pattern transfer as a whole rather than just enhancing lithography. As with any material expected to exhibit multiple roles there is a delicate balance between optimizing materials with respect to one of its roles while not impairing its other roles. We will discuss some of these conflicts and present Si-BARCs and carbon rich underlayers which aim to balance these conflicts. In this paper we will explore simulations aimed at finding the best film thicknesses and optical indices, etch rate selectivity, and lithographic performance of high silicon content and high carbon content BARC materials designed to meet the demands of both high NA lithography and trilayer processing.

Image Reversal Trilayer Materials and Processing

Image reversal trilayer (IRT) combines three lithographic patterning enhancement approaches: image reversal, spin on hard masks, and shrink for recess types of features. With IRT, photoresist imaging is done directly on top of the carbon underlayer. Thick IRT-Carbon Hard Masks (CHM) films provide effective antireflection with high NA lithography and are more etch resistant than common photoresist. IRT-Silicon Hard Masks (SiHM) can be coated over the resist patterns in the lithography track. IRT etching reverses the resist pattern into the IRT-SiHM and transfers this image to the IRTCHM. The recessed patterns in the IRT-CHM are smaller than the CD of the photoresist feature from an inherent shrinking capability of the IRT-SiHM. Continuous improvements to both IRT-SiHM and IRT-CHM have been made. Silicon contents in IRT-SiHM have been pushed as high as possible while not impacting other important properties such as stability, coating quality and resist compatibility. Newer polysiloxane IRT-SiHM no longer require resist freezing prior to coating. Carbon contents in IRTCHM have been pushed as high as possible while maintaining solubility and a low absorption which is important when resist imaging is done directly on top of the IRT-CHM. Feasibility of this image reversal trilayer process was previously demonstrated on L/S and pillar gratings. Recent work focused on nonsymmetrical 2D gratings and simultaneous patterning of L/S gratings at different pattern densities. Particular emphasis is given to pattern density effects which are applicable to any top-coating image reversal process. This paper describes the lithography, pattern transfer process and 2nd generation hard mask materials developed for IRT processing.

Double imaging with resist freezing in a vapor reaction chamber

Cost-effective approaches to double patterning are currently an area of intense interest. This paper describes an update on the progress of AZs Vapor Reaction Chamber (VRC) freeze approach to double patterning. Swift integration of the VRC process will depend on whether or not a commercial prime chamber can function as a VRC chamber without modifications. Procedures for testing this were developed and applied to a lab VRC and 2 AHD modules. Results demonstrate that for the 8in ADH the across wafer freeze uniformity is within the experimental error of the FT-IR measurements used to evaluate the process, but that some slight variation was seen for the 12in ADH. In addition, progress has been made in improving double imaging profiles over earlier work which used the same resist in both exposures on ArF 1C5D substrates. This work looked at the benefits of using different substrates, establish a suitable resist for each exposure, and using substrate treatments to improve profiles.

Spin-on trilayer scheme: enabling materials for extension of ArF immersion lithography to 32nm node and beyond

Trilayer stacks with alternating etch selectivity were developed and extensively investigated for high NA immersion lithography at 32nm node and beyond. This paper discusses the fundamental aspects of the Si-containing BARC (Si-BARC) materials with ultra-high silicon content and carbon-rich underlayers that we developed. Designing of materials at a molecular level is presented. It was demonstrated that this fundamental understanding assisted in achieving satisfactory shelf life and excellent coating defect results. Prolith® simulations using trilayer stacks showed superior reflectivity control for hyper-NA immersion lithography. The impact of high incident angles on substrate reflectivity was analyzed and this paper demonstrated that trilayer scheme provides wider process windows and is more tolerant to topography than conventional single layer BARC. Extensive resist compatibility investigation was conducted and the root causes for poor lithography results were investigated. Excellent 45nm dense lines performance employing the spin-on trilayer stack on a 1.2 NA immersion scanner is reported. In addition, pattern transfers were successfully carried out and the Si-BARC with high silicon content demonstrated outstanding masking property. In comparison to the theoretical %Si values, better correlation with etch selectivity was observed with experimental %Si. Furthermore, this paper addresses the wet rework of trilayer materials and results using Piranha rework are presented. Clean 12in wafers were obtained after reworking trilayer stacks, as evidenced by defect analysis.